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ЖУРНАЛЫ // Наносистемы: физика, химия, математика // Архив

Наносистемы: физика, химия, математика, 2024, том 15, выпуск 4, страницы 481–486 (Mi nano1292)

PHYSICS

Crystalline LiYF$_4$:Nd$^{3+}$ nanoparticles synthesized via laser ablation method in water solutions of ethanol

Anna L. Dymova, Vadim A. Prikazchikov, Anna V. Astrakhantseva, Timur M. Minnebaev, Mintimir R. Zaitov, Maksim S. Pudovkin, Alexey S. Nizamutdinov

Kazan Federal University, Kazan, Russian Federation

Аннотация: In this work, a set of crystalline LiYF$_4$:Nd$^{3+}$ nanoparticles with an average size of about 35 nm, were successfully synthesized via laser ablation method in liquid (combination of ethanol and water). The samples have trigonal structure corresponding to LiYF$_4$ host. The spectral and kinetic characteristics of the synthesized nanoparticles corresponded to the characteristics of the target LiYF$_4$:Nd$^{3+}$ bulk crystal. In particular, the luminescence decay curves for the $^4$F$_{3/2}$ $\to$ $^4$I$_{11/2}$ radiative transition (Nd$^{3+}$) are single-exponential and the decay times were around 517$\mu$s, which is typical for Nd$^{3+}$ in LiYF$_4$ host. It has been established that the decrease in the power density of laser radiation energy leads to the increase of the average particle size.

Ключевые слова: laser ablation, laser ablation in liquids, LiYF$_4$ nanoparticles, Nd$^{3+}$ nanoparticle synthesis.

Поступила в редакцию: 03.12.2023
Исправленный вариант: 18.07.2024
Принята в печать: 19.07.2024

Язык публикации: английский

DOI: 10.17586/2220-8054-2024-15-4-481-486



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