Communications

New gold(I) complexes with fluorinated tricyclic NHC ligands: synthesis and catalytic activity

P. S. Gribanov, A. N. Philippova, D. V. Vorobyeva, T. R. Akmalov, S. M. Masoud, A. F. Smol'yakov, S. N. Osipov

A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334 Moscow, Russian Federation

Аннотация: New gold (I) complexes with bulky fluorinated N-heterocyclic carbene ligands were synthesized and fully characterized. Their catalytic activity was tested in model reactions such as intramolecular hydroamination of 2-(phenylethynyl)aniline, alkyne hydration and hydrohydrazination of henylacetylene. In all studied cases new complexes demonstrated from good to excellent catalytic activities under standard conditions.

Ключевые слова: N-heterocyclic carbenes, gold complexes, synthesis, catalysis, hydroamination, alkyne hydration, hydrohydrazination.

Поступила в редакцию: 13.08.2025
Принята в печать: 17.09.2025

Язык публикации: английский

DOI: 10.71267/mencom.7896