Communications

An additive approach to the a priori determination of activation energies of thermoneutral reactions

A. F. Shestakov, T. S. Pokidova

Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, 142432 Chernogolovka, Moscow Region, Russian Federation

Аннотация: An additive approach for determining the activation energies of thermoneutral reactions is presented, which makes it possible to find the rate constants of radical reactions of H atom abstraction based on the enthalpy of these reactions and the rate constants of the corresponding symmetric reactions.

Ключевые слова: additive method, activation energy, enthalpy of reaction, increment, thermoneutral reaction.

Поступила в редакцию: 27.05.2025
Принята в печать: 06.10.2025

Язык публикации: английский

DOI: 10.71267/mencom.7835