Communications

Zinc complex as a source of highly labile non-shielded o-iminoquinone

T. N. Kocherova, R. V. Rumyantcev, V. A. Kuropatov, A. V. Piskunov, N. O. Druzhkov

G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, Russian Federation

Аннотация: Noval unstable o-iminobenzoquinone, namely, 3,4-dibenzhydryl-6-[(2,6-diisopropylphenyl)imino]cyclohex-2-en-1-one, bearing non-shielded chelating site was synthesized in the zinc coordination sphere as a neutral ligand. The bis-o-iminosemiquinonate N^II compound was prepared by the reaction of zinc o-iminoquinolate complex with Ni(CO)₄ and characterized by NMR spectroscopy and X-ray diffraction analysis.

Ключевые слова: zinc complexes, nickel complexes, redox-active ligand, o-iminoquinone, o-iminosemiquinone, X-ray diffraction

Поступила в редакцию: 01.07.2025
Принята в печать: 20.08.2025

Язык публикации: английский

DOI: 10.71267/mencom.7864

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