Communications

Synthesis of BODIPY derivatives with iodinated cobalt bis(dicarbollide)

A. A. Druzina^a, N. V. Dudarova^a, O. B. Zhidkova^a, I. D. Kosenko^a, I. V. Ananyev^b, I. B. Sivaev^a, V. I. Bregadze<sup>a

a</sup> A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334 Moscow, Russian Federation
^b N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Аннотация: The solid-state molecular structure of azido derivative of BODIPY was determined by a single-crystal X-ray diffraction; this compound was subjected to a CuI-catalyzed azide–alkyne cycloaddition with ethynyl-containing iodine cobalt bis(dicarbollides) to give the corresponding new 1,2,3-triazole conjugates. Their study by absorption– emission spectroscopy showed that the addition of a boron cluster weakened the fluorescence of the starting azido BODIPY.

Ключевые слова: cobalt bis(dicarbollide), BODIPY, alkynes, azides, ‘click’ reaction, fluorescent labeling, boron neutron capture therapy.

Поступила в редакцию: 28.04.2025
Принята в печать: 03.06.2025

Язык публикации: английский

DOI: 10.71267/mencom.7812

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