Communications

Dehydrogenation of N-ethyldodecahydrocarbazole over Pt/C catalyst in the hydrogen storage aspect

L. M. Kustov^abc, A. N. Kalenchuk^ab, V. I. Bogdan<sup>ab

a</sup> N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
^b Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation
^c National University of Science and Technology MISiS, 119991 Moscow, Russian Federation

Аннотация: The optimum conditions (T = 210 °C and V_L = 1 h^–1) were determined for the dehydrogenation of N-ethyldodecahydrocarbazole on a 3 wt% Pt/C catalyst in a flow-type catalytic unit at normal pressure. The kinetic parameters (conversion and selectivity) of the dehydrogenation process correlated well with the volumes of released hydrogen. High purity of the thus produced hydrogen was established by chromatography.

Ключевые слова: hydrogen storage, hydrogenation, dehydrogenation, Pt/C catalyst, liquid organic hydrogen carriers, N-ethyldodecahydrocarbazole.

Поступила в редакцию: 16.10.2024
Принята в печать: 09.12.2024

Язык публикации: английский

DOI: 10.71267/mencom.7652

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