Эта публикация цитируется в 1 статье

Communications

Alkali metal reduction of 1,3,2-diazagallol-2-ylidene radical derived from acenaphthene-1,2-diimine

N. L. Bazyakina, A. A. Skatova, E. V. Baranov, I. L. Fedushkin

G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, Russian Federation

Аннотация: Reduction of the open-shell gallylene [(Ar^BIG-bian)Ga:] {Ar^BIG-bian = 1,2-bis[(2,6-dibenzhydryl-4-methylphenyl)imino]acenaphthene} with one equivalent of lithium or sodium metal in THF followed by recrystallization from DME or diethyl ether affords the lithium and sodium salts of the anionic 1,3,2-diazagallol, [(Ar^BIG-bian)GaLi(DME)₃] and [(Ar^BIG-bian)GaNa(Et₂O)₂(THF)₂]. In contrast, reaction of [(Ar^BIG-bian)Ga:] with potassium gives the solvent-free derivative [(Ar^BIG-bian)K] and gallium metal.

Ключевые слова: low-valent gallium species, alkali metals, reduction, redox-active ligands, diimines.

Поступила в редакцию: 11.11.2024
Исправленный вариант: 27.12.2024

Язык публикации: английский

DOI: 10.71267/mencom.7680

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