Communications

Hydroxycarbonylation of vinyl acetate with formic acid: pathway to lactic acid and lactates

O. L. Eliseev, T. N. Bondarenko, M. V. Tsapkina

N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Аннотация: The Pd-catalyzed hydroxycarbonylation of vinyl acetate in the presence of formic acid into 2-acetoxypropionic acid is reported. The reaction proceeds chemo- and regioselectively under very mild conditions of 80 °C and 3–6 bar CO.

Ключевые слова: hydroxycarbonylation, palladium, carbon monoxide, formic acid, vinyl acetate, acetoxypropionic acid.

Поступила в редакцию: 16.10.2024
Принята в печать: 27.12.2024

Язык публикации: английский

DOI: 10.71267/mencom.7657

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