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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2022, том 32, выпуск 2, страницы 152–163 (Mi mendc599)

Эта публикация цитируется в 14 статьях

Focus Article

Superhard boron suboxide (B6O): Crystal structure, synthesis, properties, applications, and materials based thereon

S. N. Perevislov

I.V. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, St. Petersburg, Russian Federation


Аннотация: A review of reported data on the crystal structure, synthesis, and properties of boron suboxide B6O, which is a superhard material (hardness of up to 55 GPa, as measured in single crystals), and composites based on it is presented. Methods for the synthesis of B6O with a icosahedral structure and for the growing of crystals at high temperature and high pressure are described. The mechanical and operational characteristics of composite materials based on B6O are summarized; the resistance of B6O to oxidation is analyzed, and the properties of B6O–diamond and B6O–B4C composite materials are described.

Ключевые слова: Boron suboxide, B6O synthesis, B6O materials, Superhard material, Mechanical properties, B6O–diamond and B6O–B4C composites.

Язык публикации: английский

DOI: 10.1016/j.mencom.2022.03.002



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