Аннотация:
The first palladium carbene cluster, μ2-tetrakis(diphenylmethylidene)-μ2-tetraacetato-quadro-tetrapalladiurn(4Pd–Pd) Pd4(μ-CPh2)4(μ-OAc)4, has been obtained by substitution of diphenylcarbene ligands for CO groups in μ2-tetrakis(carbonyl)-μ2-tetraacetato-quadro-tetrapalladium(4Pd–Pd) Pd4(μ-CO)4(μ-OAc)4; the cluster is also the first palladium complex containing carbene ligands of the Schrock type.