Эта публикация цитируется в 3 статьях

New, Non-symmetrical 2:2 Phthalocyanines. 1,2,3,4,15,16,17,18-Octaphenyl-9,23(24)-dinitrophthalo- and 1,2,3,4,19,20,21,22-Octaphenyldiphthalo-11,29(30)-di-tert-butyl-dinaphthalocyanine Copper Complexes

V. N. Nemykin, N. B. Subbotin, N. A. Kostromina, S. V. Volkov

V.I. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

Аннотация: The reaction between tetraphenylphthalonitrile and 4-phthalonitrile or 6-tert-butylnaphthalonitrile in the presence of copper(I) chloride gives a non-statistical mixture of non-symmetrical phthalocyanines from which 2:2 complexes are separated; in the reaction between substituted phthalo- and naphthalonitriles the 2:2 complex was a major product. The splitting of the Q-band in the electronic spectra depends on the differences in the electronic structure of the fragments of the non-symmetrical molecule.

Язык публикации: английский

DOI: 10.1070/MC1995v005n02ABEH000464

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