Эта публикация цитируется в 22 статьях

The Curtius Rearrangement of Azidocarbonylfuroxans: Some Peculiarities and the Synthesis of Aminofuroxans

I. V. Ovchinnikov, A. N. Blinnikov, N. N. Makhova, L. I. Khmel'nitskii

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: The kinetics of the Curtius rearrangement of the isomeric 3(4)-azidocarbonyl-4(3)-methylfuroxans has been studied; CON₃ group rearrangement was shown to proceed faster at the 3- versus the 4-position and to be favoured by an electron-withdrawing substituent at the second ring carbon atom; a series of previously inaccessible isomeric aminofuroxans has been synthesized.

Язык публикации: английский

DOI: 10.1070/MC1995v005n02ABEH000456

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