Эта публикация цитируется в 22 статьях

Effect of spin density on the photochemical stability of aromatic nitrenes

S. V. Chapyshev

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, Russian Federation

Аннотация: FTIR studies and UB3LYP/6-31G* calculations showed that triplet nitreno-1,3,5-triazines with zero-field splitting D-parameters of |D/hc| > 1.40 cm^–1 and spin populations on the nitrene centres of ρ_N > 1.77 are photochemically very stable and do not rearrange into ring-expanded products on photolysis in cryogenic matrices.

Язык публикации: английский

DOI: 10.1070/MC2003v013n02ABEH001722

Реферативные базы данных:

•