Эта публикация цитируется в 8 статьях

Acyl C→N migration in the thioureidomethylation of 2-(4-methylbenzoyl)cyclohexanone

A. D. Shutalev^a, N. E. Zhukhlistova^b, G. V. Gurskaya<sup>c

a</sup> M.V. Lomonosov Institute of Fine Chemical Technologies, MIREA - Russian Technological University, Moscow, Russian Federation
^b A.V. Shubnikov Institute of Crystallography, FSRC ‘Crystallography and Photonics', Russian Academy of Sciences, Moscow, Russian Federaion
^c V.A. Engelhardt Institute of Molecular Biology, Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: The thioureidomethylation of the sodium enolate of 2-(4-methylbenzoyl)cyclohexanone 3 with N-(tosylmethyl)thiourea 1a or N-(azidomethyl)thiourea 2 in acetonitrile results in the unexpected formation of N-(4-methylbenzoyl)-N’-[(2-oxocyclohexyl)-methyl]thiourea 6, which was structurally characterised by X-ray diffraction analysis.

Язык публикации: английский

DOI: 10.1070/MC2004v014n01ABEH001866

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