E. N. Varaksina, V. F. Mironov, A. A. Shtyrlina, A. B. Dobrynin, I. A. Litvinov, A. I. Konovalov, “Regioselective chlorination of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes”, Mendeleev Commun., 15:3 (2005), 103

Эта публикация цитируется в 2 статьях

Regioselective chlorination of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes

E. N. Varaksina, V. F. Mironov, A. A. Shtyrlina, A. B. Dobrynin, I. A. Litvinov, A. I. Konovalov

A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation

Аннотация: The reactions of 4- and 5-methyl-2,2,2-trichlorobenzo[d]-1,3,2-dioxaphospholes with molecular chlorine in an 1:1 ratio occur selectively to give 4-methyl-2,2,2,5-tetrachloro- and 5-methyl-2,2,2,6-tetrachlorobenzo[d]-1,3,2-dioxaphospholes, which undergo hydrolysis to 4-chloro-3-methyl- and 4-chloro-5-methyl-1,2-dihydroxybenzenes, respectively.

Язык публикации: английский

DOI: 10.1070/MC2005v015n03ABEH002069