Эта публикация цитируется в 9 статьях

Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion

V. D. Kiselev

Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation

Аннотация: The volumes of electrostriction of the ions of lithium perchlorate are in a linear relation with the solvent electrostriction parameter ∂(1/ϵ)/∂p but the volume changes of ion pair transition state of electrophilic addition of aryl sulfenyl chloride to styrene and cyclohexene have the slope about 20 times less.

Ключевые слова: sulfenyl chloride; volume of activation; solvent effect; electrostriction; mechanism.

Язык публикации: английский

DOI: 10.1016/j.mencom.2008.01.022

Реферативные базы данных:

•