Эта публикация цитируется в 2 статьях

Synthesis, structure and thermal decomposition of cycloalkanone enamine peroxides

E. K. Starostin^a, V. N. Khrustalev^b, M. Yu. Antipin^b, A. V. Lalov<sup>a

a</sup> N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
^b A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences, Moscow, Russian Federation

Аннотация: Reactions of cycloalkanone enamines with H₂O₂ gave bis(1-morpholinocyclopent-1-yl)- and bis(1-morpholinocyclohex-1-yl)-peroxides, which were studied by NMR spectroscopy and X-ray diffraction. Thermolysis of bis(1-morpholinocyclohex-1-yl)-peroxide in n-hexane resulted in two major products, viz., cyclohexanone and morpholine.

Язык публикации: английский

DOI: 10.1016/j.mencom.2009.11.014

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