V. N. Losev, E. V. Buiko, A. K. Trofimtchuk, N. G. Maksimov, “Reactions of osmium in various oxidation states with mercaptopropyl and aminopropyl groups simultaneously attached to a silica gel surface”, Mendeleev Commun., 23:2 (2013), 90

Эта публикация цитируется в 2 статьях

Reactions of osmium in various oxidation states with mercaptopropyl and aminopropyl groups simultaneously attached to a silica gel surface

V. N. Losev^a, E. V. Buiko^a, A. K. Trofimtchuk^b, N. G. Maksimov^c

^a Research Engineering Centre ''Kristall'', Krasnoyarsk, Russian Federation
^b Department of Chemistry, T.G. Shevchenko Kiev National University, Kiev, Ukraine
^c Institute of Chemistry and Chemical Technology, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russian Federation

Аннотация: The sorption characteristics and diffuse reflectance and EPR spectra of osmium surface complexes showed that Os⁸⁺ and Os⁶⁺ in OsO₄ and K₂[OsO₂Cl₄], respectively, react with mercaptopropyl groups, whereas Os⁴⁺ in K₂[OsCl₆] reacts with aminopropyl groups covalently bound to a silica gel surface.

Язык публикации: английский

DOI: 10.1016/j.mencom.2013.03.012