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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2016, том 26, выпуск 6, страницы 500–501 (Mi mendc2259)

Эта публикация цитируется в 5 статьях

Communications

HUSY zeolite promoted hydrophenylation of alkynes conjugated with electron-withdrawing substituents

D. S. Ryabukhinab, A. V. Vasilyevab

a St. Petersburg State Forest Tecnical University, St. Petersburg, Russian Federation
b Institute of Chemistry, St. Petersburg State University, St. Petersburg, Russian Federation


Аннотация: Arylacetylenes, conjugated with electron-withdrawing groups, ArC≡C(EWG) [EWG = SO2Ph, PO(OEt)2, COMe, CO2Me] in reaction with benzene at room temperature or 130°C (glass high pressure tube) for 1–10h under the action of acidic zeolite HUSY (Si /Al ratio is 15) afford products of hydrophenylation of acetylene bond Ar(Ph)C=CH(EWG) in yields of 56–98%.

Язык публикации: английский

DOI: 10.1016/j.mencom.2016.11.013



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