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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2025, том 35, выпуск 3, страницы 324–326 (Mi mendc1397)

Эта публикация цитируется в 1 статье

Communications

The feasible photoinduced growth of polycyclic aromatic hydrocarbons from cosmic benzene ice

V. A. Terashkevich, E. A. Pazyuk, A. V. Stolyarov

Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation


Аннотация: The reactive phenyl radical, electronically excited benzene monomer and dimer, their radical cations and low-atomic neutral hydrocarbons may be born in situ via the photodissociation/photoionization of a gaseous benzene monomer/dimer photo-desorbed from cosmic ice as well as via the subsequent dissociative recombination of the arisen benzene cations. The above-mentioned species can be the sources for the assembly into large polycyclic aromatic hydrocarbons, which can occur at very low temperatures and pressures in the interstellar medium.

Ключевые слова: astrochemistry, polycyclic aromatic hydrocarbons, benzene excimer, cosmic photochemistry, interstellar medium, ab initio calculation.

Поступила в редакцию: 07.10.2024
Принята в печать: 15.11.2024

Язык публикации: английский

DOI: 10.71267/mencom.7639



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