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ЖУРНАЛЫ // Mendeleev Communications // Архив

Mendeleev Commun., 2020, том 30, выпуск 6, страницы 700–702 (Mi mendc1296)

Эта публикация цитируется в 5 статьях

Communications

Reaction of R-pulegone with P–H phosphonium salts

M. E. Shemakhinaab, A. V. Nemtarevab, R. R. Fayzullina, N. R. Khasiyatullinaa, L. R. Grigor’evab, V. F. Mironovab

a A.E. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center of the Russian Academy of Sciences, Kazan, Russian Federation
b Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kazan, Russian Federation


Аннотация: The reaction of the R-pulegone with P–H-phosphonium salts gives the corresponding 8-phosphonio-p-menthan-3-one salts with high regio- and stereoselectivity. The structure of salts was determined by NMR and IR spectroscopy, mass spectrometry and X-ray diffraction analysis.

Ключевые слова: phosphonium salt, R-pulegone, p-menthane, α,β-enones, terpenes, terpenoids, triphenylphosphine, addition reaction.

Язык публикации: английский

DOI: 10.1016/j.mencom.2020.11.003



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