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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2014 Volume 52, Issue 4, Pages 535–542 (Mi tvt618)

This article is cited in 29 papers

Plasma Investigations

Chemical Composition of Plasma of Dielectric Barrier Discharge at Atmospheric Pressure with a Liquid Electrode

E. S. Bobkova, Ya. V. Khodor, O. N. Kornilova, V. V. Rybkin

Ivanovo State University of Chemistry and Technology

Abstract: The composition of active particles in a plasma was calculated for the conditions of dielectric barrier discharge at atmospheric pressure in oxygen from the measured waveforms of current and voltage using joint solution of the Boltzmann equation and the equations of chemical kinetics. Kinetic equations included the reactions involving $\text{O}_2$ and $\text{H}_2\text{O}$ molecules (the main plasma gas), their dissociation products, and the excited states of molecules $\text{O}_2$ and atoms $\text{O}$. It is shown that the main neutral components of such plasma are molecules $\text{O}_3$, $\text{O}_2(a^1\Delta_g)$, $\text{H}_2\text{O}_2$, and $\text{OH}$. The mechanisms of formation and destruction of these components are studied.

UDC: 537.525+539.19

Received: 10.06.2013

DOI: 10.7868/S0040364414030053


 English version:
High Temperature, 2014, 52:4, 511–517

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© Steklov Math. Inst. of RAS, 2026