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JOURNALS // Teplofizika vysokikh temperatur // Archive

TVT, 2007 Volume 45, Issue 5, Pages 688–695 (Mi tvt1179)

This article is cited in 5 papers

Thermophysical Properties of Materials

The modified Simon equation and some properties of substances on the melting line

M. Z. Faizullin, V. P. Skripov

Institute of Thermal Physics, Ural Branch, Russian Academy of Sciences, Ekaterinburg

Abstract: Two versions of modified Simon equation, which contain a correction factor with additional parameters, are suggested for describing the melting lines of elementary substances. It is demonstrated that the generalizations found for the Simon equation (the universality of component $\Delta \tilde s_1$ of entropy of melting, the convergence of the extreme position of melting line at $T \to 0$ with the limits of thermodynamic stability of coexisting crystal and liquid, and the correlation of the pole of melting line $p_*$ with internal pressure $p_i$ in the condensed phase in the vicinity of the triple point) retain stability to the variation of the form of dependence $p_{\text{melt}} = f(T)$.

UDC: 536.421

PACS: 64.70.dv

Received: 16.05.2006


 English version:
High Temperature, 2007, 45:5, 621–627

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