I. N. Ganiev, R. S. Shonazarov, A. Elmurod, U. N. Faizulloev, “Heat capacity and thermodynamic functions of the aluminum alloy <nobr>$\rm AlCu4.5\rm Mg1$</nobr> alloyed with barium”, TVT, 2023, Volume 61, Issue 5,Pages <nobr>673

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Thermophysical Properties of Materials

Heat capacity and thermodynamic functions of the aluminum alloy $\rm AlCu4.5\rm Mg1$ alloyed with barium

I. N. Ganiev^a, R. S. Shonazarov^b, A. Elmurod^c, U. N. Faizulloev^d

^a V.I. Nikitin Institute of Chemistry
^b Bokhtar State University named after N. Khusrava, Bokhtar, Republic of Tajikistan
^c Danghara State Ubniversity, Danghara, Republic of Tajikistan
^d National Science and Research University "MISiS" Devision in Tajikistan, Dushanbe, Republic of Tajikistan

Abstract: The results of the experimental determination of the heat capacity of the aluminum alloy $\rm AlCu4.5\rm Mg1$ alloyed with barium and the calculation of the temperature dependences of changes in the thermodynamic functions of this alloy are presented. Studies of the temperature dependence of the heat capacity of the $\rm AlCu4.5\rm Mg1$ alloy alloyed with barium are carried out in the cooling mode using a computer and the Sigma Plot $10.0$ software. The types of polynomials of the temperature dependence of the heat capacity and changes in thermodynamic functions (enthalpy, entropy, and Gibbs energy) of the studied alloy and the standard $(\rm Al$ grade $\rm A5\rm N)$, which describe these changes with the correlation coefficient $R_{\text{cor}} = 0.999$, are established. It is shown that with the increasing barium content, the heat capacity of the original alloy decreases. The enthalpy and entropy of the $\rm AlCu4.5\rm Mg1$ alloy alloyed with barium increase with increasing temperature, and decrease with the increasing barium content. The Gibbs energy values have an inverse relationship.

UDC: 544.723

Received: 22.07.2022
Revised: 31.08.2022
Accepted: 13.10.2022

DOI: 10.31857/S0040364423050058