Abstract:
Generalised form of the Heisenberg Hamiltonian is proposed for crystals, the structure
units of wrich include the group of the lowest states with different orbital as well
as spin quantum numbers (the spin-orbital multiplet). The technique of irreducible
tensor operators is used for constructing the Hamiltonian. Application of the Hamiltonian
obtained to the study of orbital ordering in the model crystal with orbitally degenerated
centres is considered.