Abstract:
For a classical system of interacting particles with charges and rigid dipole moments an expansion is constructed with respect to irreducible diagrams for the single-particle distribution function by resummation of the functional series with respect to the electrostatic part of the interaction. This expansion is a series in an effective “dressed” potential, and in contrast to the original expansion does not contain long-range Coulomb divergences. As an illustration, the asymptotic behavior of the single-particle distribution function in the surface layer of a polar liquid is obtained on the basis of the direct selection and summation of the important diagrams.