This article is cited in 37 papers

Thermochemistry of the solvation of organic non-electrolytes

B. N. Solomonov, A. I. Konovalov

Kazan State University

Abstract: This review surveys experimental data on the thermochemistry of the solvation of organic non-electrolytes. An analysis of the enthalpy of solvation as the sum of the enthalpies of non-specific solvation and of specific interaction is presented. The various methods for isolating the contribution of the enthalpies of the complex formation reactions between the solute and the solvent are examined. The role of the dipole moment of the solute molecule in solvation is analysed in detail. The bibliography includes 104 references.

UDC: 536.653:547

DOI: 10.1070/RC1991v060n01ABEH001029

 English version: Russian Chemical Reviews, 1991, 60:1, 25–38

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