Abstract:
Data on fluoroalkylation and perfluoroalkylation methods in organic synthesis are analyzed, summarized and described systematically. The most practically important properties of compounds with fluoroalkyl substituents are illustrated. The key trends of the development and the potential of this field of organic chemistry are considered. Electrochemical syntheses of perfluoroalkyl derivatives that are inaccessible or experimentally difficult by regular chemical techniques are presented. Particular attention is paid to processes involving organometallic compounds as well as to prospects for the development of this field of research.
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