This article is cited in 37 papers

Preparation, properties and applications of oligomeric and polymeric organosilanes

V. V. Semenov

G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod

Abstract: The studies devoted to methods of preparation of oligomeric and polymeric organosilanes, their properties and their use are reviewed. Industrial sources, as well as processes underlying the laboratory syntheses of these compounds are analyzed. Characteristics of the silicon–silicon σ-bond and electronic interactions in oligoorganosilanes are discussed. Physicochemical properties of oligomeric and polymeric organosilanes and their known and prospective applications are considered.

Received: 08.10.2009

DOI: 10.1070/RC2011v080n04ABEH004110

 English version: Russian Chemical Reviews, 2011, 80:4, 313–339

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