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Chiral 1,3,2-oxazaborolidines in asymmetric synthesis: recent advances

V. A. Glushkov, A. G. Tolstikov

Institute of technical Chemistry of Ural branch RAS, Perm

Abstract: The use of chiral 1,3,2-oxazaborolidines in asymmetric organic synthesis, particularly, in enantioselective reduction of ketones, imines and oxime ethers, asymmetric Diels–Alder reactions, aldol condensation and atroposelective reduction of lactones is reviewed. Reactions of immobilised 1,3,2-oxazaborolidines are also considered.

Received: 11.10.2002

DOI: 10.1070/RC2004v073n06ABEH000778

 English version: Russian Chemical Reviews, 2004, 73:6, 581–608

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