This article is cited in 2 papers

Unsaturated organosilanes: synthesis, transformations and applications

M. Yu. Moskalik, B. A. Shainyan

A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, Irkutsk, Russian Federation

Abstract: The urgency of improving the efficiency of known methods and developing new ones for the synthesis of unsaturated silanes is caused by the need to obtain useful compounds, including biologically active ones, on their basis. This review considers methods for the preparation of unsaturated silanes, their transformations and prospects for their use as precursors in organic and organoelement synthesis. A large number of substituted organosilicon products are given, including those capable of further functionalization and the formation of heterocycles, including silaheterocycles.
The bibliography includes 205 references.

Keywords: alkynes; dienes; allenes; enynes; hydrosilylation; vinyl silanes, allyl silanes; silaheterocycles; vinylation; desilylation; cyclization; β-effect of silicon atom.

Received: 20.06.2024

DOI: 10.59761/RCR5140

 English version: Russian Chemical Reviews, 2024, 93:11, 1–34

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