This article is cited in 154 papers

Cation—cation interaction in crystalline actinide compounds

N. N. Krot, M. S. Grigoriev

Institute of Physical Chemistry, Russian Academy of Sciences, Moscow

Abstract: The published data on the structures and properties of crystalline actinide compounds having mutually coordinated AnO₂⁺ or AnO₂ ²⁺ cations as structural elements are surveyed. This cation—cation interaction is an important structure-forming factor for many crystalline compounds of Np(V) and U(VI). It strongly affects their UV-Vis and IR spectra as well as other properties. Differences and similarities between the cation—cation interactions of actinide ions in solutions and crystals are discussed.

Received: 27.05.2003

DOI: 10.1070/RC2004v073n01ABEH000852

 English version: Russian Chemical Reviews, 2004, 73:1, 89–100

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