This article is cited in 43 papers

Metal-catalyzed reactions for the C(sp$^{2}$)–N bond formation: achievements of recent years

I. P. Beletskaya, A. D. Averin

Lomonosov Moscow State University, Faculty of Chemistry

Abstract: The review deals with the main catalytic methods for the C(sp$^{2}$)–N bond formation, including Buchwald–Hartwig palladium-catalyzed amination of aryl and heteroaryl halides, renaissance of the Ullmann chemistry, i.e., the application of catalysis by copper complexes to form the carbon–nitrogen bond, and Chan–Lam reactions of (hetero)arylboronic acids with amines. Also, oxidative amination with C–H activation, which has been booming during the last decade, is addressed. Particular attention is paid to achievements in the application of heterogenized catalysts.
The bibliography includes 350 references.

Keywords: catalysis, amination, aryl and heteroaryl halides, aryl boronic acids, Pd and Cu complexes, immobilized catalysts.

Received: 21.08.2020

DOI: 10.1070/RCR4999

 English version: Russian Chemical Reviews, 2021, 90:11, 1359–1396

Bibliographic databases:

• 
• 
• 
•