This article is cited in 52 papers

Complexes of diamagnetic cations with radical anion ligands

I. V. Ershova, A. V. Piskunov, V. K. Cherkasov

G. A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhnii Novgorod

Abstract: The review summarizes and analyzes the currently know data on the synthesis, molecular and electronic structures and magnetic properties of bi-, tri- and tetraradical complexes containing a diamagnetic metal ion and redox-active ligands in the paramagnetic form. The bibliography includes 193 references.

Keywords: redox-active ligands, diamagnetic cations, radical anion, magnetic exchange, ground spin state, diradical, triradical, o-semiquinone, o-diiminobenzosemiquinone, alpha-bipyridine, 1,4-diaza-1,3-butadiene, (arylimino)acenaphthene, α-iminopyridine, o-iminosemiquinone.

Received: 06.04.2020

DOI: 10.1070/RCR4957

 English version: Russian Chemical Reviews, 2020, 89:11, 1157–1183

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