A. V. Ananiev, I. G. Tananaev, V. P. Shilov, “Heterogeneous catalytic redox reactions in the chemistry and technology of the nuclear fuel cycle”, Usp. Khim., 2005, Volume 74, Issue 11,Pages <nobr>1132

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Heterogeneous catalytic redox reactions in the chemistry and technology of the nuclear fuel cycle

A. V. Ananiev^a, I. G. Tananaev^b, V. P. Shilov^a

^a Institute of Physical Chemistry and Electro Chemistry, Russian Academy of Sciences, Moscow
^b Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow

Abstract: The published data on heterogeneous catalytic redox reactions involving uranium, neptunium, plutonium and americium ions in acidic and alkaline media as well as on catalytic decomposition of some organic and nitrogen-containing inorganic components of liquid inorganic wastes are generalised. The results of kinetic studies of these reactions are analysed and possible mechanisms are considered.

Received: 26.01.2005

DOI: 10.1070/RC2005v074n11ABEH001186