This article is cited in 28 papers

Recent advances in catalytic asymmetric dihydroxylation of olefins

Roman V. Ottenbacher^ab, Еvgenii P. Talsi^ab, Konstantin P. Bryliakov<sup>ab

a</sup> Novosibirsk State University
^b Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk

Abstract: Asymmetric dihydroxylation of olefinic groups is an extremely important synthetic transformation which has been widely utilized to obtain optically pure pharmaceuticals and other fine chemical products. In recent years,catalyst systems for the asymmetric C=C dihydroxylations have attracted significant interest, the major research efforts being focused on designing environmentally benign catalyst systems. This mini-review summarizes recent progress in the field, surveying both novel, less toxic modifications of the classical osmium-based catalysts, and the highly efficient and enantioselective non-osmium catalyst systems.
The bibliography includes 50 references.

Received: 05.06.2019

Language: English

DOI: 10.1070/RCR4904

 English version: Russian Chemical Reviews, 2019, 88:11, 1094–1103

Bibliographic databases:

• 
• 
• 
•