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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 2019 Volume 88, Issue 9, Pages 875–900 (Mi rcr4263)

This article is cited in 75 papers

Mechanical activation of heterogeneous exothermic reactions in powder mixtures

A. S. Rogachev

Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences

Abstract: The review concerns the results of recent experimental, theoretical and applied studies on mechanical activation of reactive powder compositions and self-propagating high-temperature synthesis of materials using activated mixtures. We discuss the influence of activation regimes on the combustion temperature and velocity, self-ignition temperature, activation energy of the reaction, as well as the microstructure and atomic structure of the reactive compositions. Particular attention is paid to revealing structural transformations that lead to an increase in the reactivity of powder mixtures. Examples of practical application of the processes reviewed are presented.
The bibliography includes 229 references.

Received: 05.03.2019

DOI: 10.1070/RCR4884


 English version:
Russian Chemical Reviews, 2019, 88:9, 875–900

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