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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 2019 Volume 88, Issue 4, Pages 387–405 (Mi rcr4250)

This article is cited in 50 papers

Fluorine in the structure of polymers: influence on the gas separation properties

Yu. P. Yampolskii, N. A. Belov, A. Yu. Alentiev

A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow

Abstract: Results of studies on the separation of gases and vapours using fluorine-containing polymers are integrated and analyzed. Methods for the synthesis of these polymers are considered, including direct gas-phase fluorination, plasma polymerization of fluorine-containing precursors and modification of organic polymers, as well as diverse syntheses of monomers containing $\mathrm{C}$$\mathrm{F}$ and $\mathrm{C}$$\mathrm{CF}_3$ bonds and their subsequent polymerization. Structure–property relationships for these polymers are elucidated and their actual and potential applications as membrane materials are discussed.
The bibliography includes 165 references.

Received: 04.10.2018

DOI: 10.1070/RCR4861


 English version:
Russian Chemical Reviews, 2019, 88:4, 387–405

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