This article is cited in 25 papers

Metal complex catalysis in the synthesis of organomagnesium compounds

U. M. Dzhemilev, A. G. Ibragimov

Institute of Petrochemistry and Catalysis of RAS, Ufa

Abstract: The published data on the synthesis of organomagnesium compounds assisted by metal complex catalysts are generalised and described systematically for the first time. Hydro-, carbo- and cyclomagnesiation reactions of unsaturated compounds with R¹MgR² (R¹ = Alk, Ar; R² = H, Hal; R¹ = R² = Alk) catalysed by Ti, Zr and other transition metal salts and complexes are considered. Selected examples of applications of organomagnesium reagents to organic synthesis are given.

Received: 25.10.2004

DOI: 10.1070/RC2005v074n09ABEH001171

 English version: Russian Chemical Reviews, 2005, 74:9, 807–823

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