K. A. Dubkov, G. I. Panov, V. N. Parmon, “Nitrous oxide as a selective oxidant for ketonization of <nobr>$\mathrm{C}=\mathrm{C}$</nobr> double bonds in organic compounds”, Usp. Khim., 2017, Volume 86, Issue 6,Pages <nobr>510

This article is cited in 27 papers

Nitrous oxide as a selective oxidant for ketonization of $\mathrm{C}=\mathrm{C}$ double bonds in organic compounds

K. A. Dubkov^a, G. I. Panov^a, V. N. Parmon^ab

^a Boreskov Institute of Catalysis SB RAS, Novosibirsk
^b Novosibirsk State University

Abstract: The oxidation chemistry of nitrous oxide $(\mathrm{N}_2\mathrm{O})$ includes a wide range of both catalytic and non-catalytic selective oxidation reactions. This review summarizes the results of modern experimental and theoretical studies devoted to non-catalytic oxidation reactions of $\mathrm{N}_2\mathrm{O}$ with carbon–carbon double bonds of alkenes and polymers. It is shown that these reactions open up a promising way for the synthesis of diverse carbonyl compounds (ketones and aldehydes) as well as a new type of functionalized oligomers — unsaturated polyketones. Possible applications of unsaturated polyketones, as well as economic aspects of $\mathrm{N}_2\mathrm{O}$ production and use as a selective oxidant are discussed.
The bibliography includes 109 references.

Received: 11.10.2016

DOI: 10.1070/RCR4697