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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 2017 Volume 86, Issue 6, Pages 474–509 (Mi rcr4165)

This article is cited in 21 papers

Light-controlled molecular switches based on carbon clusters. Synthesis, properties and application prospects

A. R. Tuktarov, A. A. Khuzin, U. M. Dzhemilev

Institute of Petrochemistry and Catalysis of RAS

Abstract: The review integrates and analyzes the experimental and theoretical studies published in the last 15 years dealing with the synthesis and physicochemical and photochromic properties of the hybrid molecules based on carbon clusters (fullerenes, nanotubes and graphene) and photochromic molecules (diarylethenes, spiropyrans, spirooxazines and azobenzene). The state-of-the-art trends of the application of photochromic compounds as light-controlled electronic devices, sensors and optical memory elements are considered. The main types of optical molecular switches derived from carbon clusters are described. The synthetic approaches to these hybrid molecules and the relationships between their structure and photochromic properties are discussed.
The bibliography includes 199 references.

Received: 01.08.2016

DOI: 10.1070/RCR4685


 English version:
Russian Chemical Reviews, 2017, 86:6, 474–509

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