This article is cited in 33 papers

Copper and nickel chelate complexes with polydentate N,O-ligands: structure and magnetic properties of polynuclear complexes

A. V. Pestov^ab, P. A. Slepukhin^ab, V. N. Charushin<sup>ab

a</sup> I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Ekaterinburg
^b Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg

Abstract: Comparative analysis of the structures of copper(II) and nickel(II) chelate complexes with N-substituted 2-aminoethanol, 3-aminopropan-1-ol, glycine and $\beta$-alanine is performed. It is shown that tetradentate ligands based on 3-aminopropan-1-ol and $\beta$-alanine, sterically hindered 2-aminoethanol derivatives and tridentate enamino ketone derivatives tend to form oligonuclear copper(II) and nickel(II) complexes. Glycine derivatives do not provide the formation of oligonuclear copper(II) and nickel(II) complexes. The magnetic properties of a number of polynuclear complexes are compared.
Bibliography — 182 references.

Received: 15.04.2014

DOI: 10.1070/RCR4461

 English version: Russian Chemical Reviews, 2015, 84:3, 310–333

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