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Cyclopalladated complexes in enantioselective catalysis

V. V. Dunina^a, O. N. Gorunova^b, P. A. Zykov^a, K. A. Kochetkov<sup>b

a</sup> Lomonosov Moscow State University, Faculty of Chemistry
^b A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow

Abstract: The results of the use of optically active palladacycles in enantioselective catalysis of [3,3]-sigmatropic rearrangements, aldol condensation, the Michael reaction and cross-coupling are analyzed. Reactions with allylic substrates or reagents and some other transformations are considered.

Received: 11.03.2010

DOI: 10.1070/RC2011v080n01ABEH004151

 English version: Russian Chemical Reviews, 2011, 80:1, 51–74

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