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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1986 Volume 55, Issue 12, Pages 2045–2066 (Mi rcr3766)

This article is cited in 9 papers

The Mechanism of the Reaction of C-Nitroso-compounds with Alkenes

L. M. Kogan

S. V. Lebedev Synthetic Rubber Research Institute, Leningrad

Abstract: Published data on the study of the chemical aspects of the reaction of C-nitroso-compounds with alkenes have been examined and critically reviewed. The multi-stage nature of the process has been emphasised. The dependence of the mechanisms of the primary stage and subsequent stages of the reaction on the structure of the reagents and the reaction conditions has been discussed. An attempt has been made to explain the contradictory data on the structure of the final reaction products in terms of the variety of possible directions for the transformation of the intermediates. The characteristics of the chemical reaction of C-nitroso-compounds with diene polymers have been examined.
The bibliography contains 117 references.

UDC: 547.331:547.313:541.124

DOI: 10.1070/RC1986v055n12ABEH003249


 English version:
Russian Chemical Reviews, 1986, 55:12, 1164–1174

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