This article is cited in 23 papers

Intramolecular Electronic Interactions in Phosphorus Compounds in the Light of Recent Structural Studies

R. P. Arshinova

Kazan State University A. Butlerov Institute of Chemistry

Abstract: The nature and mechanism of intramolecular electronic interactions in compounds of three- and four-coordinate phosphorus have been critically examined on the basis of a review of the results of the study of their three-dimensional structure and physical properties. The high π-acceptor power of phosphorus-containing groups, capable of stabilising conformations with the trans-orientation of the interacting orbitals of the donors (the n-orbitals of the unshared electron pairs of the heteroatoms or the π-orbitals of unsaturated systems) and the acceptors (bonds of the phosphorus atom) has been proved.
The bibliography contains 193 references.

UDC: 541.67:547.1.118

DOI: 10.1070/RC1984v053n04ABEH003056

 English version: Russian Chemical Reviews, 1984, 53:4, 351–368

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