This article is cited in 5 papers

Organometallic Catalysis in Diene and Cyclo-olefin Polymerisation Processes. I. The Polymerisation and Copolymerisation of Dienes Under the Influence of Organometallic Transition Metal Compounds. The Stereoregulation Mechanism

B. A. Dolgoplosk, E. I. Tinyakova

A. V. Topchiev Institute of Petrochemical Synthesis of the Academy of Sciences of the USSR, Moscow

Abstract: The results of experimental studies on the synthesis of individual organometallic transition metal compounds and of studies on their catalytic activity in stereospecific diene polymerisation and copolymerisation processes are surveyed. The kinetics of the polymerisation under the influence of various nickel-, chromium-, titanium-, and molybdenum-containing systems are examined. The stereoregulation mechanism and the principal characteristics of coordination copolymerisation are discussed on the basis of the experimental data.
The bibliography includes 125 references.

UDC: 541.64:547.315.2

DOI: 10.1070/RC1984v053n01ABEH003017

 English version: Russian Chemical Reviews, 1984, 53:1, 22–35

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