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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1983 Volume 52, Issue 4, Pages 640–668 (Mi rcr3460)

This article is cited in 15 papers

The Reactivity of 1,3,2-Diheterophospholans Containing a Tricoordinate Phosphorus Atom

M. A. Pudovika, V. V. Ovchinnikovb, R. A. Cherkasovb, A. N. Pudovika

a A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan
b Kazan State University

Abstract: The results of studies on the reactivity of 1,3,2-di-heterophosphacycloalkanes containing a tricoordinate phosphorus atom carried out in recent years are examined and surveyed. Much attention has been devoted to reactions leading to an increase of the coordination number of the ring phosphorus atom and also to exocyclic and endocyclic substitution reactions. The mechanisms and certain stereochemical characteristics of the reactions of cyclic phosphorus compounds are discussed. In a few instances the reactivities have been estimated quantitatively.
The bibliography includes 245 references.

UDC: 547.341

DOI: 10.1070/RC1983v052n04ABEH002823


 English version:
Russian Chemical Reviews, 1983, 52:4, 361–376

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