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JOURNALS // Uspekhi Khimii // Archive

Usp. Khim., 1982 Volume 51, Issue 6, Pages 881–924 (Mi rcr3392)

This article is cited in 6 papers

Oxidation of Organometallic Compounds by Transition Metal Salts

A. N. Kashin, I. P. Beletskaya

Lomonosov Moscow State University, Faculty of Chemistry

Abstract: The mechanisms of one- and two-electron oxidation of organometallic compounds by transition metal salts are considered. It is shown that organometallic compounds can be oxidised as a result of dielectric electron transfer but usually unstable transition metal compounds are formed as intermediates in the reactions. The mechanisms of the thermal and catalytic decomposition of certain types of organometallic compounds are discussed in this connection.
The bibliography includes 244 references.

UDC: 547.216:547.412

DOI: 10.1070/RC1982v051n06ABEH002856


 English version:
Russian Chemical Reviews, 1982, 51:6, 503–526

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