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Kinetics of the Thermal Decomposition of N-Nitro-compounds

F. I. Dubovitskii, B. L. Korsunskii

Institute of Chemical Physics of the USSR Academy of Sciences, Moscow

Abstract: Results primarily on nitramines are summarised. Analysis of modern views indicates that a non-chain radical mechanism with rupture of the N–NO₂ bond in the rate-determining stage is the most soundly based. Kinetic parameters of the thermal decomposition of N-nitro-compounds are systematised. The kinetic role of phase constitution is discussed, and prospects for future research are considered. A list of 108 references is included.

UDC: 541.127:547.232:547.547:547.879

DOI: 10.1070/RC1981v050n10ABEH002721

 English version: Russian Chemical Reviews, 1981, 50:10, 958–978

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