This article is cited in 18 papers

The Use of Taft Relations for the Correlation of the Properties of Organosilicon Compounds. The Role of Substituent Effects

V. P. Mileshkevich, N. F. Novikova

S. V. Lebedev Synthetic Rubber Research Institute, Leningrad

Abstract: Data for the correlations between the properties of organosilicon compounds on the basis of Taft equations are surveyed for the first time. The results for 140 relations involving reactivities, capacities for complex formation, and spectroscopic characteristics are examined. The specific features of the influence of individual effects of substituents at the silicon atom and the ability of the silicon atom and silicon-containing groups to transmit effects are discussed.
The bibliography includes 149 references.

UDC: 547'128:541,427

DOI: 10.1070/RC1981v050n01ABEH002543

 English version: Russian Chemical Reviews, 1981, 50:1, 49–62

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